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Energy Transfer from Ce3+ to Eu2+ in LiSrBO3 and Its Potential Application in UV-LED-Based White LEDs

Wang Zhi-Jun, Li Pan-Lai, Yang Zhi-Ping, Guo Qing-Lin and Fu Guang-Sheng

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CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES

Ce3+/Eu2+ codoped LiSrBO3 phosphor is synthesized, and its luminescent characteristics are investigated. LiSrBO3:Ce3+,Eu2+ phosphor exhibits varied hues from blue to white and eventually to yellow by resonance-type energy transfer from Ce3+ ion to Eu2+ ion and tuning the relative proportion of Ce3+/Eu2+ properly. Energy transfer mechanism in LiSrBO3:Ce3+, Eu2+ phosphor is dominated by the dipole-dipole interaction, and the critical distance of the energy transfer is estimated to be about 2 nm by both spectral overlap and concentration quenching methods. Under UV radiation, white light is generated by coupling 436 and 565 nm emission bands attributed to Ce3+ and Eu2+ radiations, respectively.


PACS

81.20.-n Methods of materials synthesis and materials processing

78.55.Hx Other solid inorganic materials

61.80.Ba Ultraviolet, visible, and infrared radiation effects (including laser radiation)

61.72.S- Impurities in crystals

85.60.Jb Light-emitting devices

85.60.Bt Optoelectronic device characterization, design, and modeling

Subjects

Electronics and devices

Condensed matter: electrical, magnetic and optical

Optics, quantum optics and lasers

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 6 August 2009



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