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Improvement in Dielectric Tunability of Ba0.6Sr0.4TiO4-Mg2TiO4 Composite Ceramics via Heterogeneous Nucleation Processing

Wang Zhuo1,2 and Li Yong-Xiang1

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CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES

Dielectric tunable composite ceramics Ba0.6Sr0.4 TiO3-Mg2TiO4 (BST-MT) are prepared with a heterogeneous nucleation sol-gel approach. The Mg2TiO4 powders are synthesized by the conventional solid-state reaction method. The micro-sized MT powders with dispersant Ciba-4010 are introduced into Ba-Sr-Ti sol to obtain uniform and homogeneous mixture compounds with nano-sized BST particles synthesized via heterogeneous nucleation (HN) in the sol-gel process. Thus, the microstructural and dielectric properties can be tailored. The dielectric constants of BST-MT composite ceramics can be adjusted in a large range from 294 to 1790, and the dielectric tunability can be adjusted from 29.4% to 37.0% with different MT contents from 60 wt% to 20 wt%. Compared to the samples prepared by the conventional solid-state (SS) process, the BST-MT composite ceramics by the heterogeneous nucleation sol-gel process exhibit a more uniform microstructure, and improve dielectric properties.


PACS

81.05.Mh Cermets, ceramic and refractory composites

77.84.Dy Niobates, titanates, tantalates, PZT ceramics, etc.

81.20.Fw Sol-gel processing, precipitation

77.22.Ch Permittivity (dielectric function)

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 10 April 2009



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