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Electronic Structure and Elastic Properties of Ti3AlC from First-Principles Calculations

Du Yu-Lei

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CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES

We perform a first-principles study on the electronic structure and elastic properties of Ti3AlC with an antiperovskite structure. The absence of band gap at the Fermi level and the finite value of the density of states at the Fermi energy reveal the metallic behavior of this compound. The elastic constants of Ti3AlC are derived yielding c11 = 356 GPa, c11 = 55 GPa, c44 = 157 GPa. The bulk modulus B, shear modulus G and Young's modulus E are determined to be 156, 151 and 342 GPa, respectively. These properties are compared with those of Ti3AlC2 and Ti2AlC with a layered structure in the Ti-Al-C system and Fe3AlC with the same antiperovskite structure.


PACS

71.20.Ps Other inorganic compounds

71.15.Mb Density functional theory, local density approximation, gradient and other corrections

81.20.Ev Powder processing: powder metallurgy, compaction, sintering, mechanical alloying, and granulation

62.20.D- Elasticity

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 11 May 2009



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