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Effects of Grain Boundary Barrier in ZnO/Si Heterostructure

Liu Bing-Ce, Liu Ci-Hui, Fu Zhu-Xi and Yi Bo

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CONDENSED MATTER: ELECTRONIC STRUCTURE, ELECTRICAL, MAGNETIC, AND OPTICAL PROPERTIES

The influence of ZnO microstructure on electrical barriers is investigated using capacitance-voltage (C – V), current-voltage (I – V) and deep level transient spectroscopy (DLTS) measurements. A deep level center located at Ec – 0.24 eV obtained by DLTS in the ZnO films is an intrinsic defect related to Zni. The surface states in the ZnO grains that have acceptor behavior of capturing electrons from Zni defects result in the formation of grain barriers. In addition, we find that the current transport is dominated by grain barriers after annealing at 600° C at O2 ambient. With the increment of the annealing temperature, the current transport mechanism of ZnO/Si heterostructure is mainly dominated by thermo-emission.


PACS

73.40.Lq Other semiconductor-to-semiconductor contacts, p-n junctions, and heterojunctions

73.20.At Surface states, band structure, electron density of states

61.72.Mm Grain and twin boundaries

61.72.Cc Kinetics of defect formation and annealing

71.55.Cn Elemental semiconductors

71.55.Gs II-VI semiconductors

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 11 (November 2009)

Received 8 April 2009



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