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Nitrogen Adatom Diffusion on a Ga-Rich GaN (0001) Surface

Dai Xian-Qi1,2, Wu Hua-Sheng2, Xie Mao-Hai2, Xu Shi-Hong2 and Tong Shuk-Yin3

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The diffusion of N adatoms on a Ga-rich GaN(0001) surface has been studied using density-functional theory. The configuration of Ga adatoms on a Ga-rich GaN surface has been identified. The first adlayer Ga adatoms are on top of the terminating substrate Ga atoms, and the outmost adlayer Ga adatoms exist randomly at the T4 or H3 sites. A very different diffusivity of N adatoms on a Ga-rich GaN(0001) surface has been found. The excess Ga adatoms on a GaN(0001) surface reduce the diffusion barrier by 0.75 eV and influence the migration path. It seems that bilayer Ga adatoms are helpful for N atom diffusion.


PACS

68.43.Jk Diffusion of adsorbates, kinetics of coarsening and aggregation

68.43.Fg Adsorbate structure (binding sites, geometry)

68.43.De Statistical mechanics of adsorbates

Subjects

Surfaces, interfaces and thin films

Dates

Issue 3 (March 2004)

Received 17 November 2003



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