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Etch Pits and Threading Dislocations in GaN Films Grown by Metal-Organic Chemical Vapour Deposition

Lu Min1,2,3, Chang Xin4, Li Zi-Lan1,2,3, Yang Zhi-Jian1,2,3, Zhang Guo-Yi1,2,3 and Zhang Bei1,2,3

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High quality epitaxial GaN films on (0001) sapphire substrates were grown by a commercial metal-organic chemical vapour deposition system. The, etch pits and threading dislocations in GaN films is studied by a scanning electron microscope (SEM) and a transmission-electron microscope (TEM). The SEM images of GaN films, etched in mixed acid solution (H3PO4:H2SO4 = 1:3) and molten KOH exhibit notably different, etching pit densities of 5×108/cm2 and 4×107/cm2, respectively, which probably indicate that more kinds of, etching pits were revealed when, etched in mixed acid solution (H3PO4:H2SO4 = 1:3). Cross section TEM of GaN films with different g vectors showed the portions of different threading dislocations. Theoretical calculation indicates that the lattice and thermal expansion coefficient mismatch may be the main origins of pure edge threading dislocations.


PACS

68.55.-a Thin film structure and morphology

81.15.Gh Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, etc.)

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.15.Kk Vapor phase epitaxy; growth from vapor phase

68.37.Lp Transmission electron microscopy (TEM)

Subjects

Surfaces, interfaces and thin films

Dates

Issue 3 (March 2003)

Received 11 November 2002



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