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Microstructures of GaN Films Laterally Overgrown on Si(111) by Hydride Vapour Phase Epitaxy

Chen Zhi-Zhong1,2, Zhang Rong1, Zhu Jian-Min1, Qin Zhi-Xin2, Shen Bo1, Gu Shu-Lin1, Wang Feng1, Zheng You-Dou1, Zhang Guo-Yi2, Li Zhi-Feng3 and L. F. Kuech4

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We have investigated the microstructures of GaN films laterally epitaxially overgrown (LEO) on Si(111) substrates using hydride vapour phase epitaxy. The threading dislocation density in the LEO GaN is reduced by about two orders. Different etching angles of the two sidewalls of SiO2 masks (66o and 90o) lead to the asymmetry of the LEO and cause the particular microstructures of LEO GaN. In micro-Raman spectra, the intensities vary weakly periodically about 5 µm perpendicular to the mask stripes. The indistinct selective growth in the top surface is discussed.


PACS

68.55.A- Nucleation and growth

81.15.Kk Vapor phase epitaxy; growth from vapor phase

81.65.Cf Surface cleaning, etching, patterning

78.30.Fs III-V and II-VI semiconductors

61.72.Ff Direct observation of dislocations and other defects (etch pits, decoration, electron microscopy, x-ray topography, etc.)

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Dates

Issue 3 (March 2002)

Received 13 September 2001



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