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Optical Constants of Palladium Phthalocyanine Derivative Thin Films

Wu Yi-Qun1,2, Gu Dong-Hong1, Gan Fu-Xi1, Wang Jun-Dong3 and Chen Nai-Sheng3

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Ellipsometric parameters of a series of spin-coated thin films of palladium phthalocyanine derivatives with bromine and tetraalkoxyl substitutes (PdPc(OC8H17)4Brm, m = 0,2,3,4) are determined from a rotating analyser-polarizer type of scanning ellipsometer. The optical, dielectric constants and absorption coefficients of the films in the 500-800 nm wavelength region are reported. The results show that refractive index N (N = n-k), dielectric constant ε (ε = ε12) and absorption coefficient α in the region 500-800 nm are influenced by bromine atom substituted on the conjugated phthalocyanine ring regularly. It is found that there is approximately a linear relationship between the resonance absorption wavelengths of the films and the number of bromine atoms substituted on the phthalocyanine ring.


PACS

78.66.Qn Polymers; organic compounds

78.20.Ci Optical constants (including refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity)

07.60.Fs Polarimeters and ellipsometers

42.79.Wc Optical coatings

42.70.Nq Other nonlinear optical materials; photorefractive and semiconductor materials

Subjects

Soft matter, liquids and polymers

Condensed matter: electrical, magnetic and optical

Instrumentation and measurement

Surfaces, interfaces and thin films

Optics, quantum optics and lasers

Dates

Issue 11 (November 2002)

Received 17 June 2002



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