Andrew C Todd 2002 Phys. Med. Biol. 47 507 doi:10.1088/0031-9155/47/3/311
Andrew C Todd
Show affiliationsThis paper reports on the development of an L-shell x-ray fluorescence (XRF) bone lead measurement system. A secondary target gave greater lead x-ray peak signal-to-background ratios than partially plane polarized XRF. Filtration did not improve the lead x-ray peak signal-to-background ratio: the gains in spectrum quality were outweighed by the losses caused by attenuation. There was a substantial matrix effect: the signal from a calcium-rich matrix was far lower than that from a calcium-free matrix. The effect of attenuation was, as expected, profound for the lead L x-rays: detection limits ranged from 18 to 217 μg Pb/g plaster with attenuation equivalent to 0–2.1 mm of skin or 0–3.7 mm of adipose tissue for the Pb Lα x-ray group (10.5 keV), and from 16 to 184 μg Pb/g plaster with attenuation equivalent to 0–1.3 mm of skin or 0–2.3 mm of adipose tissue for the Pb Lβ x-ray group (12.6 keV).
Issue 3 (7 February 2002)
Received 23 September 2001
Published 18 January 2002
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