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Final report on key comparison CCQM-K8 of monoelemental calibration solutions

H Felber1, M Weber1 and C Rivier2

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KEY COMPARISON

This report describes a key comparison of monoelemental calibration solutions, organized under the auspices of the Consultative Committee for Amount of Substance (CCQM) in 1999-2000 and piloted by the Federal Laboratories for Materials Testing and Research (EMPA, Switzerland) and the Laboratoire National d'Essais (BNM-LNE, France). Solutions of aluminium, copper, magnesium and iron were measured. Although different methods of measurement were applied, most of the thirteen participating national metrology institutes achieved results within the required target range for a combined standard uncertainty of 0.5 % relative for each element. The methods used were titrimetry, coulometry, gravimetry, isotope dilution mass spectrometry and inductive coupled plasma/emission spectrometry.


 

Main text. To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database www.bipm.org/kcdb.

This Final Report has been peer-reviewed and approved for publication by the CCQM according to the provisions of the Mutual Recognition Arrangement (MRA).

PACS

06.20.F- Units and standards

06.30.Dr Mass and density

82.80.Fk Electrochemical methods

82.45.Rr Electroanalytical chemistry

82.80.Ms Mass spectrometry (including SIMS, multiphoton ionization and resonance ionization mass spectrometry, MALDI)

Subjects

Instrumentation and measurement

Chemical physics and physical chemistry

Dates

Issue 1A (Technical Supplement 2002)



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