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Absolute measurement of the hyperfine splittings of six molecular 127I2 lines around the He-Ne/I2 wavelength at λ = 633 nm

H R Simonsen and F Rose

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With the aid of two diode-laser narrowband spectrometers around 633 nm, we report the measurement of the iodine hyperfine components of the R(60) 8-4, R(125) 9-4 and P(54) 8-4 transitions located −12 GHz from the classical red He-Ne laser stabilized on the R(127) 11-5 transition of 127I2, the P(33) 6-3 transition roughly −1 GHz away, the P(39) 6-3 transition 3.4 GHz above, and the R(59) 8-4 and P(53) 8-4 transitions roughly 19 GHz above. The Doppler-free absorption signals were resolved using a third-harmonic detection technique and hyperfine frequency splittings were measured by beat-frequency techniques. The individual hyperfine transitions were linked to a 633 nm He-Ne laser by direct frequency measurements up to 16 GHz. The experimental standard uncertainty was typically below 5 kHz (i.e. relative uncertainty <1 × 10−11).


PACS

33.15.Pw Fine and hyperfine structure

06.20.Dk Measurement and error theory

33.20.Vq Vibration-rotation analysis

33.20.Kf Visible spectra

Subjects

Atomic and molecular physics

Instrumentation and measurement

Dates

Issue 6 (December 2000)



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