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Pressure cell for optical studies of polymer solids and solutions in the range 10-3-109 Pa

J F Rabek, B Ranby, H Kereszti and J Sanetra

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A pressure cell for optical studies of solid (films) and liquid samples in the range 10-3-109 Pa is described. Glass ampoules with externally degassed liquid samples are broken inside an evacuated high-pressure cell. This procedure allows measurement of UV, visible, IR and emission spectra of degassed samples in vacuum or in the presence of various gases. The pressure cell has been designed for the study of charge-transfer contact complexes between oxygen and polymers and of high-pressure photo-oxidation of polymers.


PACS

78.66.Qn Polymers; organic compounds

61.25.H- Macromolecular and polymers solutions; polymer melts

82.30.Fi Ion-molecule, ion-ion, and charge-transfer reactions

62.50.-p High-pressure effects in solids and liquids

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Chemical physics and physical chemistry

Dates

Issue 5 (May 1986)



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