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Thermal growth and cathodoluminescence of Bi doped ZnO nanowires and rods

B Alemán, P Hidalgo, P Fernández and J Piqueras

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Bi doped ZnO nanowires and rods have been grown by a catalyst free evaporation–deposition method with precursors containing either ZnO and Bi2O3 or ZnS and Bi2O3 powders. The use of ZnS as a precursor was found to lead to a higher density of nano- and microstructures at lower temperatures than by using ZnO. Energy dispersive x-ray spectroscopy (EDS) shows that the Bi content in the wires and rods is in the range 0.15–0.35 at%. Bi incorporation was found to induce a red shift of the near band gap luminescence but no quantitative correlation between the shift and the amount of Bi, as measured by EDS, was observed. The IV curves of single Bi doped wires had linear behaviour at low current and non-linear behaviour for high currents, qualitatively similar to that of undoped wires.


PACS

78.60.Hk Cathodoluminescence, ionoluminescence

61.72.uj III–V and II–VI semiconductors

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

81.05.Dz II-VI semiconductors

81.07.-b Nanoscale materials and structures: fabrication and characterization

81.16.-c Methods of nanofabrication and processing

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Condensed matter: structural, mechanical & thermal

Dates

Issue 22 (21 November 2009)

Received 22 July 2009, in final form 23 September 2009

Published 26 October 2009



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