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A review of plasma enhanced chemical vapour deposition of carbon nanotubes

REVIEW ARTICLE

M Meyyappan

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TOPICAL REVIEW

Plasma enhanced chemical vapour deposition (PECVD) has been widely discussed in the literature for the growth of carbon nanotubes (CNTs) and carbon nanofibres (CNFs) in recent years. Advantages claimed include lower growth temperatures relative to thermal CVD and the ability to grow individual, free-standing, vertical CNFs instead of tower-like structures or ensembles. This paper reviews the current status of the technology including equipment, plasma chemistry, diagnostics and modelling, and mechanisms. Recent accomplishments include PECVD of single-walled CNTs and growth at low temperatures for handling delicate substrates such as glass.


PACS

81.16.-c Methods of nanofabrication and processing

61.46.Fg Nanotubes

81.15.Gh Chemical vapor deposition (including plasma-enhanced CVD, MOCVD, etc.)

81.07.De Nanotubes

52.77.Dq Plasma-based ion implantation and deposition

Subjects

Surfaces, interfaces and thin films

Plasma physics

Nanoscale science and low-D systems

Dates

Issue 21 (7 November 2009)

Received 12 May 2009, in final form 26 August 2009

Published 6 October 2009



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