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Molecular dynamics for low temperature plasma–surface interaction studies

REVIEW ARTICLE

David B Graves1 and Pascal Brault

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TOPICAL REVIEW

The mechanisms of physical and chemical interactions of low temperature plasmas with surfaces can be fruitfully explored using molecular dynamics (MD) simulations. MD simulations follow the detailed motion of sets of interacting atoms through integration of atomic equations of motion, using inter-atomic potentials that can account for bond breaking and formation that result when energetic species from the plasma impact surfaces. This paper summarizes the current status of the technique for various applications of low temperature plasmas to material processing technologies. The method is reviewed, and commonly used inter-atomic potentials are described. Special attention is paid to the use of MD in understanding various representative applications, including tetrahedral amorphous carbon film deposition from energetic carbon ions, the interactions of radical species with amorphous hydrogenated silicon films, silicon nanoparticles in plasmas, and plasma etching.


PACS

52.40.Hf Plasma-material interactions; boundary layer effects

52.65.Yy Molecular dynamics methods

52.77.Dq Plasma-based ion implantation and deposition

52.77.Bn Etching and cleaning

Subjects

Plasma physics

Dates

Issue 19 (7 October 2009)

Received 18 September 2008, in final form 15 October 2008

Published 18 September 2009



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