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Electric current during electrophoretic deposition of conjugated polymer

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Kazuya Tada1 and Mitsuyoshi Onoda

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The electric current during the electrophoretic deposition of a conjugated polymer based on polyfluorene has been studied. Thin slab vessels provide a simple path for the colloidal particles during deposition as well as minimum suspension consumption, and the transient currents during the electrophoretic deposition from a suspension containing 1.0 g l−1 of the polymer in those vessels reveal clear breaks corresponding to the transit time. The electrophoretic mobility of the colloidal particles in the suspension has been estimated to be 7.0 ± 0.6 × 10−5 cm2 V−1 s−1. The deposition of a uniform film of the polymer over a 9 cm-square utilizing the thin slab vessel has also been demonstrated.


PACS

73.61.Ph Polymers; organic compounds

82.70.Kj Emulsions and suspensions

82.70.Dd Colloids

82.45.Qr Electrodeposition and electrodissolution

81.15.Pq Electrodeposition, electroplating

68.55.A- Nucleation and growth

Subjects

Soft matter, liquids and polymers

Surfaces, interfaces and thin films

Chemical physics and physical chemistry

Dates

Issue 13 (7 July 2009)

Received 18 March 2009, in final form 25 May 2009

Published 12 June 2009



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