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A model for catalytic growth of carbon nanotubes

Sayangdev Naha and Ishwar K Puri1

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Despite the utility and promise of carbon nanotubes (CNTs), their production is generally based on empirical principles. There are only a few CNT formation models that predict the dependence of their growth on various synthesis parameters. Typically, these do not incorporate a detailed mechanistic consideration of the various processes that are involved during CNT synthesis. We address this need and present a model for catalytic CNT growth that integrates various interdependent physical and chemical processes involved in CNT production. We validate the model by comparing its predictions with one set of experimental measurements from a previous study for cobalt (Co) catalyzed growth. A brief parametric study is presented subsequently. From an application perspective, the model is able to predict the growth rate of the CNT length and its dependence on the ambient temperature and gas-phase feedstock partial pressure.


PACS

81.16.Hc Catalytic methods

81.07.De Nanotubes

Subjects

Nanoscale science and low-D systems

Dates

Issue 6 (21 March 2008)

Received 26 December 2007, in final form 24 January 2008

Published 22 February 2008



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