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Effect of zinc on the growth mechanism of zinc oxide nanostructures in the nitrogen environment

K G Saw1, Y T Lim1, G L Tan1, Z Hassan2, K Ibrahim2, F K Yam2 and S S Ng2

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The effect of zinc on the growth mechanism of zinc oxide (ZnO) nanostructures is investigated by annealing zinc-rich sputtered ZnO thin films and ZnO single crystals that are partially coated with metallic zinc (Zn). Evidence from scanning electron microscopy, x-ray photoelectron spectroscopy as well as Raman and photoluminescence measurements suggests that excess Zn may induce the growth of ZnO nanostructures. This mechanism provides the possibility of large area selective growth.


PACS

81.16.-c Methods of nanofabrication and processing

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

78.55.Et II-VI semiconductors

78.30.Fs III-V and II-VI semiconductors

68.37.Hk Scanning electron microscopy (SEM) (including EBIC)

81.40.Ef Cold working, work hardening; annealing, post-deformation annealing, quenching, tempering recovery, and crystallization

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Condensed matter: structural, mechanical & thermal

Nanoscale science and low-D systems

Dates

Issue 5 (7 March 2008)

Received 3 December 2007, in final form 17 January 2008

Published 14 February 2008



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