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Physical and electrical characterization of atomic-layer-deposited Ru nanocrystals embedded into Al2O3 for memory applications

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Min Zhang, Wei Chen, Shi-Jin Ding1, Zhi-Ying Liu, Yue Huang, Zhong-Wei Liao and David Wei Zhang

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FAST TRACK COMMUNICATION

Growth of uniformly distributed Ru nanocrystals on Al2O3 is demonstrated via atomic layer deposition using bis(cyclopentadienyl)-ruthenium and oxygen precursors. X-ray photoelectron spectroscopy analyses reveal that metallic Ru nanocrystals were formed in this experiment, and the RuO2 surface is due to oxidation of Ru when exposed to air. The metal-oxide-silicon capacitors with Ru nanocrystals embedded into Al2O3 are electrically measured, exhibiting obvious memory effects such as a large hysteresis memory window of 3.4 V for the sweeping gate voltage of −2.5/ + 8 V and a significant flat-band voltage shift of 3.2 V under the programming of 10 V/1 ms, i.e. an effective electron injection rate as fast as 1.78 × 10−6 C cm−2 ms−1. This relates to the program mechanism of direct tunnelling and a large potential well depth.


PACS

81.07.Bc Nanocrystalline materials

73.63.Bd Nanocrystalline materials

81.65.Mq Oxidation

79.60.Jv Interfaces; heterostructures; nanostructures

81.16.-c Methods of nanofabrication and processing

Subjects

Condensed matter: electrical, magnetic and optical

Surfaces, interfaces and thin films

Nanoscale science and low-D systems

Dates

Issue 3 (7 February 2008)

Received 21 October 2007, in final form 15 December 2007

Published 8 January 2008



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