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Uniform film of conjugated polymer for light-emitting device by electrophoretic deposition

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Kazuya Tada and Mitsuyoshi Onoda

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This paper reports on the electrophoretic deposition from suspensions of a polyfluorene-based conjugated polymer with various good/poor solvent ratios. It has been found that the roughness of the film strongly depends on the good/poor solvent ratio of the parent suspension. That is, rough and turbid films are obtained when the concentration of the poor solvent is high, while uniform and transparent films, which are suitable for polymer devices, can be obtained without any post-deposition treatment in the case of low poor solvent content. Fabrication of a polymer light-emitting device using the conjugated polymer film has also been demonstrated.


PACS

82.45.Mp Thin layers, films, monolayers, membranes

85.60.Jb Light-emitting devices

82.45.Qr Electrodeposition and electrodissolution

68.55.-a Thin film structure and morphology

81.15.Pq Electrodeposition, electroplating

82.45.Wx Polymers and organic materials in electrochemistry

Subjects

Soft matter, liquids and polymers

Electronics and devices

Surfaces, interfaces and thin films

Optics, quantum optics and lasers

Chemical physics and physical chemistry

Dates

Issue 3 (7 February 2008)

Received 29 October 2007

Published 7 January 2008



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