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Synthesis and optical properties of heterostructured ZnO:S/ZnO nanosaws

Syed Ghazanfar Hussain1,4, Deming Liu1,4, Xintang Huang2, Kamal Mahir Sulieman2, Jinping Liu2, Hairong Liu1 and Raihan Ur Rasool3

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Heterostructured ZnO : S/ZnO (S-doped ZnO ribbon with ZnO nanoteeth) nanosaws were synthesized by a one-step catalyst-free process through the chemical vapour transport and condensation method. Optimum selectivity and maximum nanosaw densities are obtained for growth temperatures in the range 400–450 °C. Our study suggests that the ribbons were ZnO : S while the teeth were only ZnO. Nanorods, nanoairplane, nanobelts and smooth surface nanotip-like structures were also obtained in our experiment at different growth temperatures. The photoluminescence spectrum of the nanosaws showed a strong visible emission band compared with undoped ZnO powder at room temperature. This strong visible emission in the hetrostructured nanosaws might be useful as a future UV-excited phosphor for producing bright and broad visible-wavelength light.


PACS

81.16.Hc Catalytic methods

61.46.-w Structure of nanoscale materials

78.55.Et II-VI semiconductors

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Nanoscale science and low-D systems

Dates

Issue 24 (21 December 2007)

Received 17 September 2007, in final form 31 October 2007

Published 30 November 2007



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