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Single crystal ZnO nanowires as optical and conductometric chemical sensor

E Comini, C Baratto, G Faglia, M Ferroni and G Sberveglieri

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REVIEW ARTICLE

ZnO nanowires were deposited using the vapour phase technique. The nanowires cover the substrate and appear uniform in morphology with lengths of up to several micrometres and uniform lateral size of the order of tenths of a nanometre. The electrical and optical properties of ZnO nanowires have been characterized in the presence of nitrogen oxide. Electrical measurements highlight a remarkable response even at low operating temperatures, with detection limits lower than 200 ppb and an optimal operating temperature of 100°C, while the ZnO nanowire photoluminescence is reversibly quenched by the introduction of a few ppm of NO2 even at room temperature.


PACS

61.46.-w Structure of nanoscale materials

78.55.Et II-VI semiconductors

78.67.-n Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures

82.80.-d Chemical analysis and related physical methods of analysis

73.63.-b Electronic transport in nanoscale materials and structures

07.07.Df Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing

Subjects

Condensed matter: electrical, magnetic and optical

Instrumentation and measurement

Semiconductors

Nanoscale science and low-D systems

Chemical physics and physical chemistry

Dates

Issue 23 (7 December 2007)

Received 30 March 2007, in final form 24 May 2007

Published 16 November 2007



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