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Improvement of luminescence efficiency by electrical annealing in single-layer organic light-emitting diodes based on a conjugated dendrimer

Dongge Ma1,3, J M Lupton1, R Beavington2, P L Burn2 and I D W Samuel1

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In this paper, we study the effects of electrical annealing at different voltages on the performance of organic light-emitting diodes. The light-emitting diodes studied here are single-layer devices based on a conjugated dendrimer doped with 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole as the emissive layer. We find that these devices can be annealed electrically by applying a voltage. This process reduces the turn-on voltage and enhances the brightness and efficiency. We obtained an external electroluminescence quantum efficiency of 0.07% photon/electron and a brightness of 2900 cd m-2 after 12.4 V electrical annealing, which are about 6 times and 9 times higher than un-annealing devices, respectively. The improved luminance and efficiency are attributed to the presence of a space charge field near the electrodes caused by charging of traps.


PACS

85.60.Jb Light-emitting devices

61.72.Cc Kinetics of defect formation and annealing

78.60.Fi Electroluminescence

81.40.Gh Other heat and thermomechanical treatments

Subjects

Condensed matter: electrical, magnetic and optical

Electronics and devices

Optics, quantum optics and lasers

Condensed matter: structural, mechanical & thermal

Dates

Issue 6 (21 March 2002)

Received 7 September 2001, in final form 14 November 2001

Published 5 March 2002



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