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Metastable phases in rare-earth permanent-magnet materials

REVIEW ARTICLE

Z D Zhang1,2,3, W Liu1, J P Liu2,4 and D J Sellmyer2

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TOPICAL REVIEW

A comprehensive review is given of recent advances in the study of metastable phases in rare-earth permanent magnets. The relations between the structures of the metastable and equilibrium phases and the transformations from the former to the latter are discussed. The formation of the phases is found to depend on the difference between the symmetries of the metastable and equilibrium phases. The magnetic properties of the metastable-phase rare-earth permanent magnets synthesized by various processes, such as mechanical alloying, mechanical milling, rapid quenching, hydrogenation, disproportionation, desorption and recombination, solid-state reaction, solid-gas reaction, self-flux and sputtering, are compared. The main conclusion of this article is that searching for new metastable phases with high magnetic performance will be one of the most active directions in the research on rare-earth permanent magnets.


PACS

75.50.Ww Permanent magnets

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

75.25.+z Spin arrangements in magnetically ordered materials (including neutron and spin-polarized electron studies, synchrotron-source x-ray scattering, etc.)

Subjects

Condensed matter: electrical, magnetic and optical

Dates

Issue 22 (21 November 2000)

Received 20 December 1999



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