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Fourier transform mechanical spectroscopy

R G C Arridge and P J Barham

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A powerful new experimental method of determining the dynamic mechanical behaviour of viscoelastic materials is described. The method, Fourier transform mechanical spectroscopy (FTMS), consists of superposing and deconvoluting discrete Fourier transforms obtained from a single stress relaxation experiment using a novel sampling scheme. The theory of the sampling scheme and the superposition of the transforms is described elsewhere. In this paper the authors present the results of using the new method on Nylon over the frequency range 5*10-4 to 20 Hz and temperatures from 25 to 110 degrees C. There is good agreement between the values of storage and loss moduli, obtained by means of the transform method, and those obtained by conventional means. An activation energy of 143 kcal mol-1 is obtained for the relaxation in this temperature range. The new method has considerable potential for the rapid determination of the mechanical properties of novel polymers and composites.


PACS

62.40.+i Anelasticity, internal friction, stress relaxation, and mechanical resonances

81.40.Lm Deformation, plasticity, and creep

62.20.Hg Creep

81.05.Lg Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials

Subjects

Soft matter, liquids and polymers

Condensed matter: structural, mechanical & thermal

Dates

Issue 6 (14 June 1986)



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    R G C Arridge and P J Barham 1986 J. Phys. D: Appl. Phys. 19 L89

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