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Electrical properties of hexatriacontane single crystal

K Yoshino, S Harada, J Kyokane and Y Inuishi

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A nonlinear current-voltage characteristic is observed in hexatriacontane (C36H74) single crystals and a Schottky effect or Poole-Frenkel effect mechanism is suggested as the cause. It is shown that the breakdown strength (1.5 MV cm-1) of the crystal at room temperature: (i) is much smaller than that of polyethylene (6 MV cm-1), (ii) decreases with increasing electrode distance and (iii) is temperature insensitive until the temperature nears boiling point. These results can be explained by taking into account the large electron mobility in hexatriacontane single crystal compared with that in polyethylene. The important role of the amorphous part of the electrical conduction and breakdown characteristics in polyethylene are indicated from these discussions.


PACS

73.30.+y Surface double layers, Schottky barriers, and work functions

72.20.-i Conductivity phenomena in semiconductors and insulators

77.22.Jp Dielectric breakdown and space-charge effects

Subjects

Condensed matter: electrical, magnetic and optical

Semiconductors

Surfaces, interfaces and thin films

Dates

Issue 9 (14 September 1979)



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