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Antiferrodistortive Jahn-Teller ordering in KDy(MoO4)2

M J M Leask, A C Tropper and M R Wells

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KDy(MoO4)2 is known to undergo a structural phase transition at 14.3K. Spectroscopic and magnetic studies of the behaviour of this compound at low temperatures have revealed some striking properties which suggest that the phase transition is of the Jahn-Teller type and that ordering occurs in an antiferrodistortive mode. A two-sublattice molecular-field model has been developed to account qualitatively for the observed phenomena. This is thought to be the first reported instance of antiferrodistortive Jahn-Teller ordering in a rare-earth compound.


PACS

71.70.Ej Spin-orbit coupling, Zeeman and Stark splitting, Jahn-Teller effect

75.30.Kz Magnetic phase boundaries (including magnetic transitions, metamagnetism, etc.)

64.70.K- Solid–solid transitions

71.70.Ch Crystal and ligand fields

75.30.Cr Saturation moments and magnetic susceptibilities

Subjects

Condensed matter: electrical, magnetic and optical

Condensed matter: structural, mechanical & thermal

Dates

Issue 24 (30 August 1981)



  1. Antiferrodistortive Jahn-Teller ordering in KDy(MoO4)2

    M J M Leask et al 1981 J. Phys. C: Solid State Phys. 14 3481

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