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A comment on the calculation of atomic energy levels in LS coupling using relativistic radial integrals

K G Dyall

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Relativistic effects have been included in non-relativistic term energies in some recent work by relating to non-relativistic radial integrals. It is seen that the need for a non-relativistic term energy is principally one of labelling the eigenstates of the atomic system according to some single-configuration coupling scheme, which could be achieved by a coupling transformation from the basic jj-coupled schemes used in relativistic atomic structure calculations.


PACS

31.30.J- Relativistic and quantum electrodynamic (QED) effects in atoms, molecules, and ions

31.15.-p Calculations and mathematical techniques in atomic and molecular physics

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 7 (14 April 1985)



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