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Estimation of rate coefficients for lithium fine-structure mixing induced by collisions with noble-gas atoms

A I Reznikov

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The Li*(22Pj) fine-structure transitions induced by collisions with noble-gas atoms are treated as resonant processes. Estimation of rate coefficients kj=3/2 -> j'=1/2 for Li*-He, Ar, Kr, Xe, based on Baylis' (1969) semiempirical potentials, are in good agreement with kexpt measured recently by Elward-Berry and Berry (1980). For Li*-Ne where Baylis' potentials are incorrect, the value kexpt is used to correct them.


PACS

32.10.Fn Fine and hyperfine structure

32.80.Rm Multiphoton ionization and excitation to highly excited states

34.50.Fa Electronic excitation and ionization of atoms (including beam-foil excitation and ionization)

32.10.Dk Electric and magnetic moments, polarizabilities

31.15.bu Semi-empirical and empirical calculations (differential overlap, Hückel, PPP methods, etc.)

34.80.Dp Atomic excitation and ionization

Subjects

Atomic and molecular physics

Computational physics

Dates

Issue 5 (14 March 1982)



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